Sitka is the ideal stuff. It's light and it's strong and it doesn't splinter easily and it takes glue well. Its chief drawback is its cost, and that's due to its scarcity, with so many of the big trees that the best wood comes from having been cut already, and the remaining trees in protected parks.
Sure, there are alternatives. Some of them are far away. Some of them are available here, but Douglas fir is seeing the same problem as spruce: big trees gone, smaller trees presenting knots and other defects. And it's heavier, and weight is always the enemy. That's one factor that newbies often don't take seriously, and their airplanes can end up as real dogs. There have been homebuilts that came out with empty weights that were close to their design gross weights. They are little more than lawn ornaments that cost years of work and a lot of dollars.
Certified wood? Who certifies it? Some guy that knows what to look for, that's all. FAA's AC3.13-1B has everything one needs to know about good wood. It doesn't come from some certified tree or certified logger, though if they plan to sell it as high-quality wood they'll be careful to avoid falling it across other logs and bending or bruising it. Airplanes aren't the only things made from it; violins and their bigger brothers, wooden ladders, some other stuff. You are competing with those people when you buy it. If you use an alternative wood, you have to apply similar criteria to it. You, the builder, essentially certify it.
I grew up in lumber country. My dad and grandfather and several uncles were in that industry. Grandpa was a lumber grader. I used to stand next to him while he inspected the lumber moving along the green chain, stamping each piece with a grade stamp. Used a crayon on some: C for clear (nice wood, some of it would have made airplanes) and X (cull, throwaway stuff, sold real cheap). X was truly bad wood. The #1, 2, and 3 grades were really nice. Went into house construction.
Now I go to Home Depot or any other lumberyard and look, sadly, at what they offer. A lot of it would have been marked "X" by Grandpa, and it's stamped #2. None of it is clear. Rounded on two corners where the bark used to be. Twisted or curved or split. Knots falling out of it, big pitch pockets. Clear stuff is in the fancy-wood section, and costs about 500 times as much as it did when I was a kid. None of it is any good for aircraft, as its grain is flat, not edge-grain or within 45° of edge.
Which is one reason I would choose aluminum or tube-and-rag for a new airplane.