The P-51A through D models is the 45-100, and its coordinates are hard to come by, but it has a leading edge radius that looks like it is about 1%c. That is pretty small. No one on here is attempting to persuade you to use the 45-100.
All of this is your choice, I am just trying to make sure you have all of the pieces to the puzzle. I am concerned that a bunch of other stuff will not scale quite right and that this one topic is distracting you from the rest of them. Span to fuselage length will likely not scale, nor will wing to tail proportions. Cockpit area is likely to be big, and so on.
23015 leading edge radius is 2.48%, 23012 is 1.58% and the 63-x15 64-x15, and Riblett 37A315 all have 1.58%. At the tip, there is no difference, and at the root, yeah it would be small, but let's look at the rest of the wing. Tank put on a speed strake, mostly to fit the main landing gear wheels, and its proportions seem to have been chosen for that purpose. You probably will face that challenge too. You can certainly put on any leading edge radius on the strake you want at the fuselage and blend it to the airfoil to make things look right.
If you go ahead with 23015/23012, be prepared for tip stalls and other bad behaviour. Find that in your tests and you get to choose between a clean airfoil that looks right but behaves badly, or the same foil with some seriously non-period correct stall strips at the root, VG's on the outboard part of the wing, and who knows what else to make it behave. I doubt that either result will be desireable. Maybe a clean wing that behaves well is worth what I believe is a subtle looks issue.
Alternatives are still the Riblett laminar flow foils (35A315 and 37A315) and Riblett turbulent foils (30A315). Compare them to the 23015 and ask yourself if this distinction really matters. The leading edges are not that much different. The strake at the fuselage can further help with the feel of the real thing. Then get on with how to make the planform look right when you have the fuselage big enough for people, the wing big enough for your desired stall speed, and the tail big enough to control the whole thing. Then comes structures. Have fun.
Billski